CSS - Dreamweaver

Hi everyone I'm a newbie in the community and also with ethe whole web design thing. I have dreamweaver mx in my computer and I opened an account in freewebs a while ago, I thought about using HTML cause it seems easier but when I try that and insert a table to create the whole body of the page I have no idea how to make the links in the right to go to the main frame, If I use frames they get all messy and I really like how CSS turns out but I am not sure how to use the links in the right. Does anyone know of any tutorials? I tried googling some but they are not being that helpful.

I want something like this - http://www.freewebs.com/sweethoneysvideos/

And when I try to paste like style code it won't work so I have no idea. I worked in CSS and it was looking really good but I have no idea how to make the links to open in the mainframe.

Can someone please help me?

ETA: Sorry I am such a rambler and I usually can't explain myself the way I want to sorry.